Issue 22, 1990
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and crystal structure of a square planar tetra-cobalt complex with two quadruply-bridging sulphur atoms [(η5-Cp)4Co4(µ4-S)2]

Feilong Jiang,   Xinjian Lei,   Zhiying Huang,   Maochun Hong,   Beisheng Kang,   Daxu Wu  and  Hanqin Liu  

Abstract

The cluster compound [(η5-Cp)4CO4(η4-S)2] was isolated from the reaction between [(η5-Cp)Co(PR3)2] and Li2S at 60 ·C; the tetramer is capped by two quadruply-bridging sulphur atoms above and below the Co4 square plane to form a distorted octahedral core Co4S2 as shown by X-ray single crystal structural analysis.

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Article information

DOI
https://doi.org/10.1039/C39900001655
Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1655-1656

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Synthesis and crystal structure of a square planar tetra-cobalt complex with two quadruply-bridging sulphur atoms [(η5-Cp)4Co4(µ4-S)2]

F. Jiang, X. Lei, Z. Huang, M. Hong, B. Kang, D. Wu and H. Liu, J. Chem. Soc., Chem. Commun., 1990, 1655 DOI: 10.1039/C39900001655

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