Issue 22, 1990

Intramolecular β,γ-addition of allylic alkoxyl radicals. A new general synthesis of α-iodoepoxides by photolysis of allylic alcohol hypoiodites in the presence of mercury(II) oxide, iodine and pyridine in benzene

Abstract

The formation of α-iodoepoxides arising from an intramolecular β,γ-addition of an allylic alkoxyl radical is a major general process in the photolysis of tertiary and some secondary allylic alcohol hypoiodites in the presence of iodine and pyridine in benzene.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 1629-1631

Intramolecular β,γ-addition of allylic alkoxyl radicals. A new general synthesis of α-iodoepoxides by photolysis of allylic alcohol hypoiodites in the presence of mercury(II) oxide, iodine and pyridine in benzene

H. Suginome and J. B. Wang, J. Chem. Soc., Chem. Commun., 1990, 1629 DOI: 10.1039/C39900001629

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