The extremely reactive and unselective 2-lithiomethyl-quinoline 1 can be titanated with an excess of Ti(OPri)4 or ClTi(OPri)3 to produce titanium analogues which react chemoselectively with carbonyl compounds.
M. T. Reetz and T. Wünsch, J. Chem. Soc., Chem. Commun., 1990, 1562 DOI: 10.1039/C39900001562
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