Linear molecular aggregation in solution: EXAFS studies of ML4 complexes
Abstract
Analysis of Pt or Ir LIII-edge EXAFS spectra for K2[Pt(CN)4]0.3Br·3H2O (1), K2[Pt(CN)4]·3H2O (2), [Pt(CNMe)3Et]PF6(3), and [Ir(CNMe)4]Cl (4) in solid and solution phases shows evidence for metal ⋯ metal interactions in solid (1), (3), and (4) and in solutions of (4).