The tricarbonyl(2-menthoxy-5-methylcyclohexadienylium)iron hexafluorophosphate (4) prepared from p-menthoxytoluene can be obtained as a single diastereoisomer and displays excellent regioselectivity with a model nucleophile providing a route to homochiral 4-substituted 4-methylcyclohex-2-enones; other related homochiral synthons are also prepared.
G. A. Potter and R. Mccague, J. Chem. Soc., Chem. Commun., 1990, 1172 DOI: 10.1039/C39900001172
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