Reaction between bis(cyclopentadienyl)titanacyclobutanes (1) and tetrakis(trifluoromethyl)cyclopentadienone (2) results in formal reductive elimination of cyclopropanes and activation of an sp3 C–F bond in (2) to afford the novel organometallic product (3)(structurally characterized by X-ray crystallography).
M. J. Burk, D. L. Staley and W. Tumas, J. Chem. Soc., Chem. Commun., 1990, 809 DOI: 10.1039/C39900000809
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