A carbotricycle (9) related to the phorbol skeleton has been constructed via low temperature Intramolecular Diels–Alder reaction of furans at ambient pressure, permitting control of the relative stereochemistry between the trans-fused A–B ring junction and the stereocentres established in the 7-oxabicyclo[2.2.1]hept-2-ene moiety of the adduct.
L. M. Harwood, G. Jones, J. Pickard, R. M. Thomas and D. Watkin, J. Chem. Soc., Chem. Commun., 1990, 605 DOI: 10.1039/C39900000605
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