Issue 8, 1990
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis, structure, and facile oxidation of a novel 1,1′-bis(N,N-dimethylaminomethyl)ferrocene bridged diplatinum complex

Christine E. L. Headford,   R. Mason,   P. Ramini Ranatunge-Bandarage,   Brian H. Robinson  and  Jim Simpson  

Abstract

The reaction of cis-PtCl2(dmso)2(dmso = dimethylsulphoxide) with the ferrocenyl amine (η5-Me2NCH2C5H4)2Fe yields the readily oxidised, cyclometallated derivative [η5-PtCl(dmso)Me2NCH2C5H3]2Fe through the intermediary of the complex [η5-trans-PtCl2(dmso)Me2NCH2C5H4]2Fe; an X-ray study of the cyclometallated species shows that the ferrocenyl bridged Pt atoms are located one above the other at a separation of 4.285(5)Å.

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Article information

DOI
https://doi.org/10.1039/C39900000601
Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 601-603

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Synthesis, structure, and facile oxidation of a novel 1,1′-bis(N,N-dimethylaminomethyl)ferrocene bridged diplatinum complex

C. E. L. Headford, R. Mason, P. R. Ranatunge-Bandarage, B. H. Robinson and J. Simpson, J. Chem. Soc., Chem. Commun., 1990, 601 DOI: 10.1039/C39900000601

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