The bimetallic complex [(η5-C5Me5)Fe(CO)2{µ-η1,η6-CH(OMe)CH2C6Me5}Fe(η5-C5H5)][PF6](3), which is readily prepared by electrophilic carbene–alkene coupling between (1) and (2), is specifically converted into either the η6-vinylpentamethylbenzene complex (4) or the related dinuclear (µ-η1, η6-vinylarene) complex (E)-(5).
V. Guerchais, J. Chem. Soc., Chem. Commun., 1990, 534 DOI: 10.1039/C39900000534
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