The enantioselective synthesis of trans-(3R,4S)-1-(R)-α-methylbenzyl-3-(2,2,5,5-tetramethyl-1-aza-2,5-disilacyclopentyl)-4-N-(R)-α-methylbenzyliminoazetidin-2-one has been accomplished by reaction of the chiorozinc enolate of an N,N-diprotected glycine ethyl ester with a Chiral α-diimine.
F. H. van der Steen, H. Kleijn, A. L. Spek and G. van Koten, J. Chem. Soc., Chem. Commun., 1990, 503 DOI: 10.1039/C39900000503
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