Issue 6, 1990

Tritylation, methoxymethylation, and silylation of allylic hydroperoxides via stannyl peroxide intermediates. Allylic rearrangement of a stannyl peroxide

Abstract

Whereas primary and secondary allylic hydroperoxides are quantitatively converted by tributyltin methoxide into stannyl peroxides, whose treatment with trityl chloride, chloromethyl methyl ether, and t-butyldimethylsilyl trifluoromethane-sulphonate give the corresponding trityl, methoxymethyl, and silyl peroxides, a tertiary allylic hydroperoxide gives rearrangement products on stannylation and treatment with trityl chloride.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 448-449

Tritylation, methoxymethylation, and silylation of allylic hydroperoxides via stannyl peroxide intermediates. Allylic rearrangement of a stannyl peroxide

R. K. Haynes and S. C. Vonwiller, J. Chem. Soc., Chem. Commun., 1990, 448 DOI: 10.1039/C39900000448

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