Nickel-catalysed coupling of orthothioesters with MeMgl furnishes a general method for introducing the Isopropenyl group; the application of this reaction to the synthesis of 1,3-(bis-trimethylsilyl)propenes is presented.
Y. Tzeng, T. Luh and J. Fang, J. Chem. Soc., Chem. Commun., 1990, 399 DOI: 10.1039/C39900000399
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