The preferred C2 conformation of CH2(SeH)2, the total stabilization energy (8.1 kJ mol–1) evaluated from the isodesmic equation (1), and the favourable 3p(Se)–σ*(C–Se) orbital interaction are in accord with weak negative hyperconjugation.
U. Salzner and P. von Ragué Schleyer, J. Chem. Soc., Chem. Commun., 1990, 190 DOI: 10.1039/C39900000190
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