Issue 2, 1990
From the journal:

Journal of the Chemical Society, Chemical Communications

Carbon–phosphorus bond cleavage and carbon–carbon bond formation at a di-iron centre: formation of ethyl acrylate via extrusion of methylene from bis(diphenylphosphino)methane

Graeme Hogarth,   Selby A. R. Knox  and  Michael L. Turner  

Abstract

Treatment of [Fe2(CO)6(µ-CO)(µ-Ph2PCH2PPh2)] with ethyl diazoacetate under UV irradiation gives [Fe2(CO)6(µ-CHCO2Et)(µ-Ph2PCH2PPh2)], which on heating undergoes double P–CH2 bond cleavage and C–C bond formation, forming CH2[double bond, length half m-dash]CH(CO2Et) and [Fe2(CO)6(µ-PPh2)2].

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39900000145
Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 145-146

Permissions

Request permissions

Carbon–phosphorus bond cleavage and carbon–carbon bond formation at a di-iron centre: formation of ethyl acrylate via extrusion of methylene from bis(diphenylphosphino)methane

G. Hogarth, S. A. R. Knox and M. L. Turner, J. Chem. Soc., Chem. Commun., 1990, 145 DOI: 10.1039/C39900000145

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements