Issue 1, 1990

N-functionalized amino-aluminium and -boron complexes: intramolecular aromatic nitrogen-assisted formation of aminoboranes

Abstract

Reaction of 6-methyl-2-bis(trimethylsilyl)pyridine or 8-bis(trimethylsilyl)aminoquinoline with BCl3 in hexane results in facile elimination of ClSiMe3 affording an aminodichloroborane, (2) or (5a), then a novel aminobis(dichloroborane), (3) or (6); compounds (3) and (5b), prepared from a lithium reagent and AlCl3, have been structurally authenticated using X-ray diffraction data.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 89-91

N-functionalized amino-aluminium and -boron complexes: intramolecular aromatic nitrogen-assisted formation of aminoboranes

L. M. Engelhardt, G. E. Jacobsen, P. C. Junk, C. L. Raston and A. H. White, J. Chem. Soc., Chem. Commun., 1990, 89 DOI: 10.1039/C39900000089

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