Imidazole has been attached at C(2) on the more open face of β-cyclodextrin to mimic the enzyme chymotrypsin; this chemical model is shown to be catalytically far superior to that with an imidazole on the primary side [C(6)] of cyclodextrin.
K. R. Rao, T. N. Srinivasan, N. Bhanumathi and P. B. Sattur, J. Chem. Soc., Chem. Commun., 1990, 10 DOI: 10.1039/C39900000010
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