Excited-state metal–molecule reactions [Hg(3P1)+ H2, Ca(1P1)+ HCl] have been studied within the complexes formed by the reactants. Under these conditions specific aspects of orbital orientation within the molecular frame are exemplified.
C. Jouvet, M. C. Duval, B. Soep, W. H. Breckenridge, C. Whitham and J. P. Visticot, J. Chem. Soc., Faraday Trans. 2, 1989, 85, 1133 DOI: 10.1039/F29898501133
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