Template condensation of 2,6-diformyl-p-cresol with 3,6-dioxa-1,8-octanediamine in the presence of lanthanide nitrates, yields homodinuclear macrocyclic complexes; solution of the structure of the gadolinium complex confirms encapsulation of a lanthanide cation pair in the macrocycle and luminescence of Eu3+ indicates Eu–Eu interactions.
I. A. Kahwa, S. Folkes, D. J. Williams, S. V. Ley, C. A. O'Mahoney and G. L. McPherson, J. Chem. Soc., Chem. Commun., 1989, 1531 DOI: 10.1039/C39890001531
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