Observation of an amplified isotope effect to the value of 19.10 indicated that there were two kinetically significant proton transfers and deprotonation of the σ-complex was the rate determining step.
M. De Rosa and M. Marquez, J. Chem. Soc., Chem. Commun., 1989, 1466 DOI: 10.1039/C39890001466
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