A new set of parameters for 1–3 interactions around the pentaco-ordinate phosphorus atom adapted to Allinger's 1977 force field, has been worked out and tested on phosphorane structures.
G. Robinet, M. Barthelat, V. Gasmi and J. Devillers, J. Chem. Soc., Chem. Commun., 1989, 1103 DOI: 10.1039/C39890001103
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