The problem of generating rot-2′-enonic acid stereospecifically with tritium in the 1′R- and 1′S-benzylic positions of the prenyl group is solved by a method generally applicable to o-prenylphenols: chiral centres are constructed on a ring system, with subsequent ring scission.
P. Bhandari, L. Crombie, M. H. Harper, M. Sanders and D. A. Whiting, J. Chem. Soc., Chem. Commun., 1989, 981 DOI: 10.1039/C39890000981
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