The vinamidine boron difluoride (difluorodiazaborinane)(1) acts as a 6-electron donor ligand in the tricarbonylchromium complex (3); the X-ray structure of (3) shows (1) to be a ligand analogous to cyclohexadienide.
N. Kuhn, A. Kuhn, R. Boese and N. Augart, J. Chem. Soc., Chem. Commun., 1989, 975 DOI: 10.1039/C39890000975
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