Issue 13, 1989
From the journal:

Journal of the Chemical Society, Chemical Communications

Facile interconversion of terminal, doubly bridging, and quadruply bridging carbonyl ligands in solution: crystal structure and solution dynamics of the complexes LWRu3(CO)12H, L = C5H5 and C5Me5

Yun Chi,   Fang-Jy Wu,   Bang-Ji Liu,   Chwan-Chin Wang  and  Sue-Lein Wang  

Abstract

The crystal structures of the tetranuclear mixed-metal complexes LWRu3(CO)12H, L = C5H5 and C5Me5, were determined, indicating the presence of a butterfly arrangement with an unusual µ4-η2-CO ligand; in solution, these isomers are in equilibrium with other isomers containing only normal σ-bonded CO ligands.

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Article information

DOI
https://doi.org/10.1039/C39890000873
Article type
Paper

J. Chem. Soc., Chem. Commun., 1989, 873-875

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Facile interconversion of terminal, doubly bridging, and quadruply bridging carbonyl ligands in solution: crystal structure and solution dynamics of the complexes LWRu3(CO)12H, L = C5H5 and C5Me5

Y. Chi, F. Wu, B. Liu, C. Wang and S. Wang, J. Chem. Soc., Chem. Commun., 1989, 873 DOI: 10.1039/C39890000873

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