Five meta-substituted sodium phenylsulphamates (from a series of 23 ortho-, meta-, and para-compounds synthesised) are sweet, X-ray crystal structure analysis and MNDO calculations show that the present dihedral angle theory fails to account for the taste of these compounds.
W. J. Spillane, M. B. Sheahan, J. M. Simmie, D. Cunningham, P. McArdle and T. Higgins, J. Chem. Soc., Chem. Commun., 1989, 545 DOI: 10.1039/C39890000545
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