Issue 8, 1988

Ring expansion in dimetallacycle chemistry: preparation of a dimetallacyclopentanol from a dimetallacyclobutane

Abstract

Treatment of the dimetallacyclobutane complex [(OC)3Fe(µ-dppm){µ-C([double bond, length half m-dash]CH2)CH2}Pt(PPh3)](dppm = Ph2PCH2PPh2) with an excess of LiBHEt3 followed by methanol quantitatively gave the dimetallacyclopentanol complex [(OC)2Fe(µ-dppm){µ-σ:η3-CH(OH)C([double bond, length half m-dash]CH2)CH2}Pt(PPh3)].

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1988, 2235-2237

Ring expansion in dimetallacycle chemistry: preparation of a dimetallacyclopentanol from a dimetallacyclobutane

X. L. R. Fontaine, G. B. Jacobsen and B. L. Shaw, J. Chem. Soc., Dalton Trans., 1988, 2235 DOI: 10.1039/DT9880002235

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