A technique based on the formation of metallic complexes has been developed to synthesize a new mixed oxide of the perovskite structural type. Electron diffraction and microscopy of LaCaMnCoO6 shows this phase to be cubic with a cell parameter a= 7.666(1)Å, double that of a perovskite basic cell. The results are discussed in terms of ordering of both A and B sublattices of the perovskite structure.
M. Vallet-Regí, E. García and J. M. González-Calbet, J. Chem. Soc., Dalton Trans., 1988, 775 DOI: 10.1039/DT9880000775
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