Trapping of the lithium dienolate (1), derived from 3-methyl-2-butenoate, with Me3GeX (X = Br or Cl) gives the α-germylated derivative (2), which reacts with various electrophiles at the γ-position.
Y. Yamamoto, S. Hatsuya and J. Yamada, J. Chem. Soc., Chem. Commun., 1988, 1639 DOI: 10.1039/C39880001639
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