A study of the fate of the hydrogen atoms in the biosynthesis of viridicatumtoxin using (13C,2H)-labelled mevalonolactones established that a 1,3-hydride shift occurs in the formation of the spirobicyclic ring system.
R. M. Horak, V. J. Maharaj, S. F. Marais, F. R. van Heerden and R. Vleggaar, J. Chem. Soc., Chem. Commun., 1988, 1562 DOI: 10.1039/C39880001562
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...