Cu–Zn and Cu–Al catalysts generated by reduction of Cu(acac)2(acac = acetylacetonato) with ZnEt2 or AlEt3, are shown to produce oxygenated compounds from syngas in the liquid phase under pressure; high selectivities for ethanol are observed, especially with the Cu–Zn system (45.7 mol%) in the early stages of the reaction.
M. Simon, A. Mortreux and F. Petit, J. Chem. Soc., Chem. Commun., 1988, 1445 DOI: 10.1039/C39880001445
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