Issue 21, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

Ruthenium catalysed oxidation of alkanes with alkylhydroperoxides

Tai-Chu Lau,   Chi-Ming Che,   Wai-On Lee  and  Chung-Kwong Poon  

Abstract

The cis-[RuII(L)2(OH2)2]2+ complexes (L = substituted 2,2′-bipyridines or 1,10-phenanthrolines) catalyse oxidation of saturated hydrocarbons to alcohols and ketones by t-butylhydroperoxide; the low values of kinetic isotope effect (kH/kD= 3.5 for cyclohexane) and tertiary of secondary C–H bond relative reactivities (ktert/ksecca. 6.5 for adamantane) are in a range expected for hydrogen atom abstraction by radical species.

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Article information

DOI
https://doi.org/10.1039/C39880001406
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1406-1407

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Ruthenium catalysed oxidation of alkanes with alkylhydroperoxides

T. Lau, C. Che, W. Lee and C. Poon, J. Chem. Soc., Chem. Commun., 1988, 1406 DOI: 10.1039/C39880001406

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