Free radical mediated ring expansion of cis- and trans-α-substituted-β-stannylcyclohexanones provides efficient routes to cis- and trans-cyclononenones and cyclodecenones; the cis-/trans-geometry of the precursor controls the alkene geometry of the ring-expanded product.
J. E. Baldwin, R. M. Adlington and J. Robertson, J. Chem. Soc., Chem. Commun., 1988, 1404 DOI: 10.1039/C39880001404
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