Issue 19, 1988
From the journal:

Journal of the Chemical Society, Chemical Communications

Substitution on five µ-oxo/µ-sulphido incomplete cuboidal MoIV3 ions [Mo3OxS4–x(H2O)9]4+: kinetic effects resulting from the replacement of core oxo by sulphido ligands

Bee-Lean Ooi,   Manuel Martinez  and  A. Geoffrey Sykes  

Abstract

A 570-fold spread in rate constants (25 °C), [H+]= 2.0 M, is observed for 1 : 1 NCS– substitution (of H2O) at Mo on the title complexes, with replacement of core µ3(O) by µ3(S) decreasing (factor of 10), and further replacement of the three µ2(O) by µ2(S) increasing (factor of 570) the rate of substitution.

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Article information

DOI
https://doi.org/10.1039/C39880001324
Article type
Paper

J. Chem. Soc., Chem. Commun., 1988, 1324-1325

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Substitution on five µ-oxo/µ-sulphido incomplete cuboidal MoIV3 ions [Mo3OxS4–x(H2O)9]4+: kinetic effects resulting from the replacement of core oxo by sulphido ligands

B. Ooi, M. Martinez and A. G. Sykes, J. Chem. Soc., Chem. Commun., 1988, 1324 DOI: 10.1039/C39880001324

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