On treatment of the carbene complexes (1a–f) with N,N-dimethylformamide dialkyl acetals (DMF-DAA)(2a–d) as electrophiles, the nature of the products, (3) or (4), depends on the structure of the starting carbene complexes.
L. Lattuada, E. Licandro, A. Papagni, S. Maiorana, A. C. Villa and C. Guastini, J. Chem. Soc., Chem. Commun., 1988, 1092 DOI: 10.1039/C39880001092
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