By means of ab initio calculations, unusually short interatomic distances are predicted between the nonbonded atoms in the title compounds and interpreted in terms of small extent of back electron-donation from the linked oxygens and the accompanying orbital contraction around the nonbonded atoms.
S. Nagase, T. Kudo and T. Kurakake, J. Chem. Soc., Chem. Commun., 1988, 1063 DOI: 10.1039/C39880001063
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