Molybdenum subcarbonyl species encaged in a zeolite, particularly in LiY, showed a high activity for the selective hydrogenation of buta-1,3-diene to cis-but-2-ene (>96%), providing the first example of hydrogenation activity of molybdenum subcarbonyl species immobilized on inorganic matrices.
Y. Okamoto, A. Maezawa, H. Kane and T. Imanaka, J. Chem. Soc., Chem. Commun., 1988, 380 DOI: 10.1039/C39880000380
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