The direction of the carbonyl orientation in solid amide rotamers of 3-(N-methyl-N-α-methylbenzylcarbamoyl)-1,2,4-trimethylpyridinium iodide is governed by the (R)- or (S)-chirality in the amide side chain; X-ray structures and c.d. spectra are correlated.
L. A. M. Bastiaansen, T. J. M. Vermeulen, H. M. Buck, W. J. J. Smeets, J. A. Kanters and A. L. Spek, J. Chem. Soc., Chem. Commun., 1988, 230 DOI: 10.1039/C39880000230
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