A non-hydrolytic procedure has been developed for cleavage of complex acetals/glycosides in which one of the acetal oxygen atoms undergoes oxidative, bromine-induced addition to a remote olefinic centre, with formation of a tetrahydrofuran ring, which is subsequently cleaved reductively with zinc.
D. R. Mootoo, V. Date and B. Fraser-Reid, J. Chem. Soc., Chem. Commun., 1987, 1462 DOI: 10.1039/C39870001462
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