The largest recorded primary (10.7%) and secondary (3.0%) deuterium isotope effects on spin-spin coupling constants have been observed for 1J(119Sn,H) in the 119Sn n.m.r. spectrum of NaSnH3-nDn(n≤ 3).
R. E. Wasylishen and N. Burford, J. Chem. Soc., Chem. Commun., 1987, 1414 DOI: 10.1039/C39870001414
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