Issue 18, 1987
From the journal:

Journal of the Chemical Society, Chemical Communications

Transient photochemistry of (η5-cyclopentadienyl)bis(ethene)rhodium

Simon T. Belt,   David M. Haddleton,   Robin N. Perutz,   Brian P. H. Smith  and  Andrew J. Dixon  

Abstract

On laser flash photolysis, using both u.v.–visible and i.r. detection, of CpRh(C2H4)2(Cp =η5-C5H5) in hydrocarbon solutions two transients are detected, A and B; A is assigned as CpRh(C2H4)(probably a triplet state) and decays to products and B via first-order kinetics [k=(1.0 ± 0.5)× 106 s–1]; B [CpRh(C2H4)S, S = solvent] reacts with incoming ligands via second-order saturation kinetics with a strong solvent dependence.

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Article information

DOI
https://doi.org/10.1039/C39870001347
Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1347-1349

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Transient photochemistry of (η5-cyclopentadienyl)bis(ethene)rhodium

S. T. Belt, D. M. Haddleton, R. N. Perutz, B. P. H. Smith and A. J. Dixon, J. Chem. Soc., Chem. Commun., 1987, 1347 DOI: 10.1039/C39870001347

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