The complex [Pt2(µ-S)(µ-dppm)(σ-dppm)2](dppm = Ph2PCH2PPh2) prepared by reaction of [Pt2(µ-dppm)3] with COS, acts as a tridentate (P2S donor) ligand for square planar metal atoms and hence gives homonuclear (Pt3) or heteronuclear (Pt2M, M = Pd, Rh, or Ir) complexes, which show unusual fluxional behaviour involving sulphur inversion.
N. Hadj-Bagheri and R. J. Puddephatt, J. Chem. Soc., Chem. Commun., 1987, 1269 DOI: 10.1039/C39870001269
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