Issue 15, 1987

1,3-Migration of a methyl group from tin to silicon via a cationic intermediate

Abstract

Reactions of (Me3Si)2C(SnMe3)(SiMe2l) with AgY (Y = O2CMe, O2CCF3, or O3SCF3) give exclusively (Me3Si)3CSnMe2Y; i.e. 1,3-migration of an Me group from an Sn to an Si atom occurs, apparently within an intermediate cation in which an Me group bridges between these atoms.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 1183-1184

1,3-Migration of a methyl group from tin to silicon via a cationic intermediate

S. M. Dhaher, C. Eaborn and J. D. Smith, J. Chem. Soc., Chem. Commun., 1987, 1183 DOI: 10.1039/C39870001183

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