Two representatives of the 10-vertex family of tricarbaboranes, arachno-µ-6,9-RCH-9-R-5,6,9-C3B7H11(R = H or Me) and nido-5,6,10-Me3-5,6,10-C3B7H8, arise from two different modes of alkyne insertion (acetylene and but-2-yne) into the cage of arachno-4,5-C2B7H13.
B. Štibr, T. Jelinek, Z. Janoušek, S. Heřmánek, E. drdáková, Z. Plzák and J. Plešek, J. Chem. Soc., Chem. Commun., 1987, 1106 DOI: 10.1039/C39870001106
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