Volumes of activation for the aquation of a series of Cr(NH3)5L3+ ions are all negative with an average value of ca.-6 cm3 mol–1, contrasting with an average positive value of ca.+2 cm3 mol–1 for the Cobalt(III) analogues, and supporting disparate associative (Ia) and dissociative (Id) mechanisms, respectively.
G. A. Lawrance and R. van Eldik, J. Chem. Soc., Chem. Commun., 1987, 1105 DOI: 10.1039/C39870001105
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