Issue 11, 1987

The synthesis and X-ray structure of the heterometallic tetranuclear butterfly cluster complex, [Fe2Rh2(CO)8{µ-Ph2PC([double bond, length half m-dash]CH2)PPh2}2]

Abstract

Treatment of the heterometallic complex [(OC)4Fe{µ-Ph2PC([double bond, length half m-dash]CH2)PPh2}RhCl(CO)] with Me3NO affords the tetranuclear cluster [Fe2Rh2(CO)8{µ-Ph2PC([double bond, length half m-dash]CH2) PPh2}2] which has been characterised by X-ray crystallography as having a butterfly structure with wing-tip Rh atoms.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 826-827

The synthesis and X-ray structure of the heterometallic tetranuclear butterfly cluster complex, [Fe2Rh2(CO)8{µ-Ph2PC([double bond, length half m-dash]CH2)PPh2}2]

R. H. Dawson and A. K. Smith, J. Chem. Soc., Chem. Commun., 1987, 826 DOI: 10.1039/C39870000826

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements