Issue 8, 1987

Electrochemically-induced and electron transfer chain-catalysed substitution reactions in dinuclear molybdenum carbonyl complexes [(η5-C5H5)2Mo2(CO)4(η-SR)2] and [(η5-C5H5)2Mo2(CO)4(η-SR)2]2+[A]2(R = Me, Ph; A = BF4 or PF6)

Abstract

A radical cation, transiently produced in a single step two-electron transfer, is shown to be the reactive species in a substitution process which can be oxidatively-induced or catalysed via an electron transfer chain mechanism.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1987, 557-559

Electrochemically-induced and electron transfer chain-catalysed substitution reactions in dinuclear molybdenum carbonyl complexes [(η5-C5H5)2Mo2(CO)4(η-SR)2] and [(η5-C5H5)2Mo2(CO)4(η-SR)2]2+[A]2(R = Me, Ph; A = BF4 or PF6)

M. Guéguen, J. E. Guerchais, F. Y. Pétillon and J. Talarmin, J. Chem. Soc., Chem. Commun., 1987, 557 DOI: 10.1039/C39870000557

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