The dissociation of carbon monoxide is induced at low temperatures by an oxygen transient present at aluminium surfaces in carbon monoxide–dioxygen (100 : 1) mixtures; a metastable surface carbonate is first formed which is deoxygenated in the temperature range 120–295 K.
A. F. Carley and M. W. Roberts, J. Chem. Soc., Chem. Commun., 1987, 355 DOI: 10.1039/C39870000355
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