A stereoselective synthesis of (E)-α-hydroxy-1,3-dienes, by thermal extrusion from adducts of 2,5-dihydrothiophene S,S-dioxide (1) with aldehydes and ketones, is presented and its extension to the synthesis of the dienone, (E)-tagetone, and of a 1,3,5-triene system, is illustrated.
S. Yamada, H. Suzuki, H. Naito, T. Nomoto and H. Takayama, J. Chem. Soc., Chem. Commun., 1987, 332 DOI: 10.1039/C39870000332
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