The dimerisation of the potassium alkoxide of methallyl alcohol to give mainly lactols (3) may be rationalised in terms of a redox system incorporating a stepwise ene reaction in which hydride transfer precedes carbon–carbon bond formation.
I. A. G. El Karim and W. B. Motherwell, J. Chem. Soc., Chem. Commun., 1987, 194 DOI: 10.1039/C39870000194
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