Photolysis of the sodium salt of phenylsulphamic acid (1, Na) yields the isomeric aniline sulphonic acids (2)–(4) and aniline (5); the involvement of an intramolecular radical rearrangement and two triplet states in the photoreaction are supported.
J. M. Lally and W. J. Spillane, J. Chem. Soc., Chem. Commun., 1987, 8 DOI: 10.1039/C39870000008
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