Issue 8, 1986

A correlation between half-wave and ionization potentials for indoles and indolizines

Abstract

Half-wave oxidation potentials (E1/2), in acetonitrile at a platinum electrode, and gas-phase ionization potentials (P) have been measured for a number of indole and indolizine derivatives, variously substituted on the five-membered ring. Except for a few compounds, a linear correlation of P vs. E1/2 was found. Deviations from linearity are discussed in terms of conformation differences between the two phases and P value uncertainties in those cases where the vibrational fine structure was resolved.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1986, 1229-1231

A correlation between half-wave and ionization potentials for indoles and indolizines

M. Colonna, L. Greci, M. Poloni, G. Marrosu, A. Trazza, F. P. Colonna and G. Distefano, J. Chem. Soc., Perkin Trans. 2, 1986, 1229 DOI: 10.1039/P29860001229

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